Gold nanoparticles have been finely tuned at Brown University to create a catalyst that selectively converts carbon dioxide (CO2) to carbon monoxide (CO), which can then be used to make alternative fuels.
‘Our study shows potential of carefully designed gold nanoparticles to recycle CO2 into useful forms of carbon,’ said Shouheng Sun, professor of chemistry and one of the study’s senior authors. ‘The work we’ve done here is preliminary, but we think there’s great potential for this technology to be scaled up for commercial applications.’
The findings are published in the Journal of the American Chemical Society.
CO2 is a stable molecule that must be reduced to an active form like CO to make it useful for creating synthetic natural gas, methanol, and other alternative fuels.
Prior research has shown that catalysts made of gold foil are active for this conversion, but they aren’t efficient. The gold tends to react with the CO2 and with the water in which the CO2 is dissolved, creating hydrogen byproduct rather than CO.
The Brown experimental group, led by Sun and Wenlei Zhu, a graduate student in Sun’s group, wanted to see if shrinking the gold down to nanoparticles might make it more selective for CO2.
They found that the nanoparticles were more selective, but that the exact size of those particles was important. Eight nanometre particles had the best selectivity, achieving a 90 per cent rate of conversion from CO2 to CO. Other sizes the team tested – four, six, and 10 nanometres – didn’t perform as well.
‘At first, that result was confusing,’ said Andrew Peterson, professor of engineering and also a senior author on the paper. ‘As we made the particles smaller we got more activity, but when we went smaller than eight nanometres, we got less activity.’
To understand what was happening, Peterson and postdoctoral researcher Ronald Michalsky used a modelling method called density functional theory. They were able to show that the shapes of the particles at different sizes influenced their catalytic properties.
‘When you take a sphere and you reduce it to smaller and smaller sizes, you tend to get many more irregular features — flat surfaces, edges and corners,’ Peterson said in a statement. ‘What we were able to figure out is that the most active sites for converting CO2 to CO are the edge sites, while the corner sites predominantly give the by-product, which is hydrogen. So as you shrink these particles down, you’ll hit a point where you start to optimize the activity because you have a high number of these edge sites but still a low number of these corner sites. But if you go too small, the edges start to shrink and you’re left with just corners.’
Now that they understand exactly what part of the catalyst is active, the researchers are working to further optimize the particles. ‘There’s still a lot of room for improvement,’ Peterson said. ‘We’re working on new particles that maximize these active sites.’
The researchers believe these findings could be an important new avenue for recycling CO2 on a commercial scale.
‘Because we’re using nanoparticles, we’re using a lot less gold than in a bulk metal catalyst,’ Sun said. ‘That lowers the cost for making such a catalyst and gives the potential to scale up.’
The work was funded by a US National Science Foundation grant to the Brown-Yale Center for Chemical Innovation (CCI), which looks for ways to use CO2 as a sustainable feedstock for large-scale commodity chemicals.
Source: The Engineer